mccoy Posted March 6, 2018 Report Share Posted March 6, 2018 Allegedly, the seasoning of wine (esp red wine) in oak barrels provides further benefits: From teh wiki voice Acutissimin A is a flavono-ellagitannin, a type of tannin formed from the linking of a flavonoid with an ellagitannin. In 2003, scientists at Institut Européen de Chimie et Biologie in Pessac, Francefound that when the oak tannin vescalagin interacts with a flavanoid in wine acutissimin A is created. In separate studies this phenolic compound has been shown to be 250 times more effective than the pharmaceutical drug Etoposide in stopping the growth of cancerous tumors.[1][2][3] Link to comment Share on other sites More sharing options...
Sibiriak Posted March 6, 2018 Report Share Posted March 6, 2018 Thanks for that Mccoy! It just so happens that I'd read something vague about the effects of oak barrel aging on wine, and I took up sipping oak-aged Cabernet Sauvignon and Malbec wines from Argentina (which happened to be on the shelves in my neck of the woods.) I like the verbal flair in this abstract: Angew Chem Int Ed Engl. 2013 Oct 25;52(44):11530-3. doi: 10.1002/anie.201305839. Epub 2013 Sep 13. Remarkable biomimetic chemoselective aerobic oxidation of flavano-ellagitannins found in oak-aged wine. https://www.ncbi.nlm.nih.gov/pubmed/24039115 AbstractUnder the auspices of Bacchus! Acutissimins, natural flavano-ellagitannins, occur in oak-aged wine as a result of a diastereoselective condensation reaction of the flavan-3-ol catechin, a component of grapes, with the C-glucosidic ellagitannin vescalagin, found in oak. The acutissimins are further converted into natural mongolicains and analogues of camelliatannin G in a remarkably chemoselective fashion by simple aerobic oxidation. Link to comment Share on other sites More sharing options...
mccoy Posted March 6, 2018 Author Report Share Posted March 6, 2018 The authors really cater to the inherent geekeness of orthorexists, I love it! Abstract Under the auspices of Bacchus! Acutissimins, natural flavano-ellagitannins, occur in oak-aged wine as a result of a diastereoselective condensation reaction of the flavan-3-ol catechin, a component of grapes, with the C-glucosidic ellagitannin vescalagin, found in oak. The acutissimins are further converted into natural mongolicains and analogues of camelliatannin G in a remarkably chemoselective fashion by simple aerobic oxidation. Link to comment Share on other sites More sharing options...
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